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Mechanisms behind the accelerated extracellular electron transfer in

Feng ZHANG,Shengsong YU,Jie LI,Wenwei LI,Hanqing YU

《环境科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 531-538 doi: 10.1007/s11783-015-0793-y

摘要： Modification of electrode surface with carboxylic acid terminated alkanethiol self-assembled monolayers (SAMs) has been found to be an effective approach to improve the extracellular electron transfer (EET) of electrochemically active bacteria (EAB) on electrode surface, but the underlying mechanism behind such enhanced EET remains unclear. In this work, the gold electrodes modified by mercapto-acetic acid and mercapto-ethylamine (Au-COOH, Au-NH ) were used as anodes in microbial electrolysis cells (MECs) inoculated with DL-1, and their electrochemical performance and the bacteria-electrode interactions were investigated. Results showed that the redox reaction occurred on the Au-NH with a higher rate and a lower resistance than that on the Au or the Au-COOH. Both the MECs with the Au-COOH and Au-NH anodes exhibited a higher current density than that with a bare Au anode. The biofilm formed on the Au-COOH was denser than that on bare Au, while the biofilm on the Au-NH had a greater thickness, suggesting a critical role of direct EET in this system. This work suggests that functional groups such as –COOH and-NH could promote electrode performance by accelerating the direct EET of EAB on electrode surface.

关键词： biofilm     extracellular electron transfer (EET)     Geobacter sulfurreducens DL-1     gold     self-assembled monolayers    

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Simultaneous Feammox and anammox process facilitated by activated carbon as an electron shuttle for autotrophic

《环境科学与工程前沿（英文）》 2022年 第16卷 第7期 doi: 10.1007/s11783-021-1498-z

摘要：

• The autotrophic nitrogen removal combining Feammox and Anammox was achieved.

关键词： Feammox     Anammox     Extracellular electron transfer     Electron shuttle     Activated carbon    

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Enhancement of extracellular Cr(VI) reduction for anammox recovery using hydrazine: performance, pathways

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1715-z

摘要：

● N2H4 addition enhanced and recovered anammox performance under Cr(VI) stress.

关键词： Extracellular Cr(VI) reduction     Electron transfer     Anammox     Hydrazine     Cr(VI) inhibition    

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Integrated energy view of wastewater treatment: A potential of electrochemical biodegradation

《环境科学与工程前沿（英文）》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1486-3

摘要：

• Energy is needed to accelerate the biological wastewater treatment.

关键词： Biological wastewater treatment     Integrated energy view     Electroactive bacteria     Extracellular electron transfer    

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Electroactivity of the magnetotactic bacteria AMB-1 and MSR-1

《环境科学与工程前沿（英文）》 2023年 第18卷 第4期 doi: 10.1007/s11783-024-1808-3

摘要：

● The first study of electrochemically active magnetotactic bacteria.

关键词： Magnetotactic bacteria     Magnetospirillum magneticum     Magnetospirillum gryphiswaldense     Extracellular electron transfer     Microbial fuel cells    

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Insights into the electron transfer mechanisms of permanganate activation by carbon nanotube membrane

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1706-0

摘要：

● A CNT filter enabled effective KMnO4 activation via facilitated electron transfer.

关键词： KMnO4     Carbon nanotubes     Non-radical pathway     Electron transfer     Water treatment    

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precise-acting” strategies for improving anaerobic methanogenesis of organic waste: Insights from the electrontransfer system of syntrophic partners

《环境科学与工程前沿（英文）》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1508-1

摘要： Methanogenesis is the last step in anaerobic digestion, which is usually a rate-limiting step in the biological treatment of organic waste. The low methanogenesis efficiency (low methane production rate, low methane yield, low methane content) substantially limits the development of anaerobic digestion technology. Traditional pretreatment methods and bio-stimulation strategies have impacts on the entire anaerobic system and cannot directly enhance methanogenesis in a targeted manner, which was defined as “broad-acting” strategies in this perspective. Further, we discussed our opinion of methanogenesis process with insights from the electron transfer system of syntrophic partners and provided potential targeted enhancing strategy for high-efficiency electron transfer system. These “precise-acting” strategies are expected to achieve an efficient methanogenesis process and enhance the bio-energy recovery of organic waste.

关键词： Methanogenesis     Anaerobic digestion     Enhancing strategy     Electron transfer     Organic waste    

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Potential of electron transfer and its application in dictating routes of biochemical processes associated

《医学前沿（英文）》 2021年 第15卷 第5期   页码 679-692 doi: 10.1007/s11684-021-0866-1

摘要： Metabolic reprogramming, such as abnormal utilization of glucose, addiction to glutamine, and increased de-novo lipid synthesis, extensively occurs in proliferating cancer cells, but the underneath rationale has remained to be elucidated. Based on the concept of the degree of reduction of a compound, we have recently proposed a calculation termed as potential of electron transfer (PET), which is used to characterize the degree of electron redistribution coupled with metabolic transformations. When this calculation is combined with the assumed model of electron balance in a cellular context, the enforced selective reprogramming could be predicted by examining the net changes of the PET values associated with the biochemical pathways in anaerobic metabolism. Some interesting properties of PET in cancer cells were also discussed, and the model was extended to uncover the chemical nature underlying aerobic glycolysis that essentially results from energy requirement and electron balance. Enabling electron transfer could drive metabolic reprogramming in cancer metabolism. Therefore, the concept and model established on electron transfer could guide the treatment strategies of tumors and future studies on cellular metabolism.

关键词： metabolic reprogramming     potential of electron transfer     cell proliferation     aerobic glycolysis     cancer metabolism    

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Algal biomass derived biochar anode for efficient extracellular electron uptake from

Yan-Shan Wang, Dao-Bo Li, Feng Zhang, Zhong-Hua Tong, Han-Qing Yu

《环境科学与工程前沿（英文）》 2018年 第12卷 第4期 doi: 10.1007/s11783-018-1072-5

摘要：

Algal biochar anode produced higher biocurrent compared with graphite plate anode.

Algal biochar exhibited stronger electrochemical response to redox mediators.

Algal biochar showed excellent adsorption to redox mediators.

关键词： Algal biochar     Anode material     Electrochemical activity     Extracellular electron transport     Waste resource utilization    

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4-Amino-1,8-naphthalimide based fluorescent photoinduced electron transfer (PET) pH sensors as liposomal

Miguel Martínez-Calvo, Sandra A. Bright, Emma B. Veale, Adam F. Henwood, D. Clive Williams, Thorfinnur Gunnlaugsson

《化学科学与工程前沿（英文）》 2020年 第14卷 第1期   页码 61-75 doi: 10.1007/s11705-019-1862-8

摘要： Four new fluorescent sensors ( - ) based on the 4-amino-1,8-naphthalimide fluorophores ( ) have been synthesized based on the classical fluorophore-spacer-receptor model. These four compounds all gave rise to emission bands centred at 535 nm, which were found to be highly pH dependent, the emission being ‘switched on’ in acidic media, while being quenched due to PET from the amino moieties to the excited state of the at more alkaline pH. The luminescent pH dependence for these probes was found to be highly dependent on the substitution on the imide site, as well as the polyamine chain attached to the position 4-amino moiety. In the case of sensor the presence of the 4-amino-aniline dominated the pH dependent quenching. Nevertheless, at higher pH, PET quenching was also found to occur from the polyamine site. Hence, is better described as a receptor -spacer -fluorophore-spacer -receptor system, where the dominant PET process is due to (normally less favourable) ‘directional’ PET quenching from the 4-amino-aniline unit to the site. Similar trends and pH fluorescence dependences were also seen for and . These compounds were also tested for their imaging potential and toxicity against HeLa cells (using DRAQ5 as nuclear stain which does now show pH dependent changes in acidic and neutral pH) and the results demonstrated that these compounds have reduced cellular viability at moderately high concentrations (with IC values between ca. 8‒30 µmol∙L ), but were found to be suitable for intracellular pH determination at 1 µmol∙L concentrations, where no real toxicity was observed. This allowed us to employ these as lysosomal probes at sub-toxic concentrations, where the based emission was found to be pH depended, mirroring that seen in aqueous solution for , with the main fluorescence changes occurring within acidic to neutral pH.

关键词： sensors     pH     photoinduced electron transfer     cellular imaging     confocal microscopy    

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Sulfur cycle as an electron mediator between carbon and nitrate in a constructed wetland microcosm

Wenrui Guo, Yue Wen, Yi Chen, Qi Zhou

《环境科学与工程前沿（英文）》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1236-y

摘要： • Fe(III) accepted the most electrons from organics, followed by NO3‒, SO42‒, and O2. • The electrons accepted by SO42‒ could be stored in the solid AVS, FeS2-S, and S0. • The autotrophic denitrification driven by solid S had two-phase characteristics. • A conceptual model involving electron acceptance, storage, and donation was built. • S cycle transferred electrons between organics and NO3‒ with an efficiency of 15%. A constructed wetland microcosm was employed to investigate the sulfur cycle-mediated electron transfer between carbon and nitrate. Sulfate accepted electrons from organics at the average rate of 0.84 mol/(m3·d) through sulfate reduction, which accounted for 20.0% of the electron input rate. The remainder of the electrons derived from organics were accepted by dissolved oxygen (2.6%), nitrate (26.8%), and iron(III) (39.9%). The sulfide produced from sulfate reduction was transformed into acid-volatile sulfide, pyrite, and elemental sulfur, which were deposited in the substratum, storing electrons in the microcosm at the average rate of 0.52 mol/(m3·d). In the presence of nitrate, the acid-volatile and elemental sulfur were oxidized to sulfate, donating electrons at the average rate of 0.14 mol/(m3·d) and driving autotrophic denitrification at the average rate of 0.30 g N/(m3·d). The overall electron transfer efficiency of the sulfur cycle for autotrophic denitrification was 15.3%. A mass balance assessment indicated that approximately 50% of the input sulfur was discharged from the microcosm, and the remainder was removed through deposition (49%) and plant uptake (1%). Dominant sulfate-reducing (i.e., Desulfovirga, Desulforhopalus, Desulfatitalea, and Desulfatirhabdium) and sulfur-oxidizing bacteria (i.e., Thiohalobacter, Thiobacillus, Sulfuritalea, and Sulfurisoma), which jointly fulfilled a sustainable sulfur cycle, were identified. These results improved understanding of electron transfers among carbon, nitrogen, and sulfur cycles in constructed wetlands, and are of engineering significance.

关键词： Constructed wetland     Sulfur cycle     Electron transfer     Denitrification    

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Synthesis, spectroscopic, and electrochemical properties of two dyads consisted of tetrathiafulvalene and carbazole

Guoqiao LAI, Yibo LIU, Meijiang LI, Yongjia SHEN

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 192-195 doi: 10.1007/s11705-009-0015-x

摘要： Two donor-σ-acceptor molecules containing tetrathiafulvalene (TTF) and carbazole moieties were synthesized by the reaction of 9-(4-bromo-butyl)-carbazole ( ) with 2,6-bis(hexylthio)-3-(2-cyanoethylthio)-7-(methylthio)-tetrathiafulvalene ( ) or 2,6-bis(2-cyanoethylthio)-3,7-bis(methylthio)tetrathiafulvalene ( ) in the presence of CsOH·H O, respectively. The structures of the molecules were characterized by H NMR, C NMR, MS, and elemental analyses. They showed negligible intramolecular charge-transfer interaction in their ground states as indicated by their UV-Vis spectroscopics and cyclic voltammetry results. Compared with carbazole, their fluorescence was strongly quenched, which implied that a photo induced electron transfer (PET) interaction between TTF and carbazole moieties occurred.

关键词： donor-σ-acceptor molecule     intramolecular charge transfer interaction     photo induced electron transfer     tetrathiafulvalene     carbazole    

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Decellularized extracellular matrix mediates tissue construction and regeneration

《医学前沿（英文）》 2022年 第16卷 第1期   页码 56-82 doi: 10.1007/s11684-021-0900-3

摘要： Contributing to organ formation and tissue regeneration, extracellular matrix (ECM) constituents provide tissue with three-dimensional (3D) structural integrity and cellular-function regulation. Containing the crucial traits of the cellular microenvironment, ECM substitutes mediate cell–matrix interactions to prompt stem-cell proliferation and differentiation for 3D organoid construction in vitro or tissue regeneration in vivo. However, these ECMs are often applied generically and have yet to be extensively developed for specific cell types in 3D cultures. Cultured cells also produce rich ECM, particularly stromal cells. Cellular ECM improves 3D culture development in vitro and tissue remodeling during wound healing after implantation into the host as well. Gaining better insight into ECM derived from either tissue or cells that regulate 3D tissue reconstruction or organ regeneration helps us to select, produce, and implant the most suitable ECM and thus promote 3D organoid culture and tissue remodeling for in vivo regeneration. Overall, the decellularization methodologies and tissue/cell-derived ECM as scaffolds or cellular-growth supplements used in cell propagation and differentiation for 3D tissue culture in vitro are discussed. Moreover, current preclinical applications by which ECM components modulate the wound-healing process are reviewed.

关键词： decellularized extracellular matrix     3D culture     organoids     tissue repair    

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Biosorption of Cu(II) to extracellular polymeric substances (EPS) from

Xiangliang PAN, Jing LIU, Wenjuan SONG, Daoyong ZHANG

《环境科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 493-497 doi: 10.1007/s11783-012-0416-9

摘要： Biosorption of extracellular polymeric substances (EPS) from sp. (cyanobacterium) with Cu(II) was investigated using fluorescence spectroscopy. Three fluorescence peaks were found in the excitation-emission matrix (EEM) fluorescence spectra of EPS. Fluorescence of peak A (Ex/Em= 275/452 nm) and peak C (Ex/Em= 350/452 nm) were originated from humic-like substances and fluorescence of peak B (Ex/Em= 275/338 nm) was attributed to protein-like substances. Fluorescence of peaks A, B, and C could be quenched by Cu(II). The effective quenching constants (lg K ) were 2.8–5.84 for peak A, 6.4–9.24 for peak B, and 3.48–6.68 for peak C, respectively. The values of lg K showed a decreasing trend with increasing temperature, indicating that the quenching processes were static in nature. The binding constants (lg K ) followed the order of peak A>peak B>peak C, implying that the humic-like substances in EPS have greater Cu(II) binding capacity than the protein-like substances. The binding site number, , in EPS-Cu(II) complexes for peaks A, B, and C was less than 1. This suggests the negative cooperativity between multiple binding sites and the presence of more than one Cu binding site.

关键词： biosorption     conditional binding constant     extracellular polymeric substances (EPS)     fluorescence quenching    

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流动电极微生物电合成提高产物生成速率及降低能量消耗 Article

褚娜, 王东麟, 王厚锋, 梁勤军, 常佳丽, 高瑜, 蒋永, 曾建雄

《工程（英文）》 2023年 第25卷 第6期   页码 157-167 doi: 10.1016/j.eng.2021.09.015

摘要：

微生物电合成（microbial electrosynthesis, MES）利用可再生电力驱动微生物固定CO2合成化学品，在推进碳循环经济中具有一定潜力，受到广泛关注。但是，很少有研究通过高效反应器设计来促进产乙酸并降低能耗。本研究中，新型流动电极MES反应器的总产乙酸速率[(16 ± 1) g·m−2·d−1]比无粉末活性炭（powder activated carbon, PAC）对照[(8 ± 3) g·m−2·d−1]高两倍。流动电极MES反应器的库伦效率为43.5% ± 3.1%，能量消耗为(0.020 ± 0.005) kWh·g−1，产乙酸的能量效率为18.7% ± 1.3%。基于PAC的流动电极能够降低水跨膜通量、传质阻力，但是对装置电压、流变行为、乙酸吸附的影响较小。流动电极MES反应器中，能量代谢相关基因高表达，Acetobacterium的丰度增加。MES反应器中同时存在用于碳固定的还原性乙酰辅酶A途径（Wood–Ljungdahl pathway, WLP）与还原性三羧酸循环途径（reductive citric acid cycle, rTCA）。堆叠型流动电极MES中的乙酸浓度达7.0 g·L−1。本研究提供一种构建可扩展MES反应器的新方法，促进CO2利用以及产物生成。

关键词： CO2利用     生物阴极     宏转录组     微生物电化学技术     胞外电子传递    

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标题 作者 时间 类型 操作

Mechanisms behind the accelerated extracellular electron transfer in

Feng ZHANG,Shengsong YU,Jie LI,Wenwei LI,Hanqing YU

期刊论文

Simultaneous Feammox and anammox process facilitated by activated carbon as an electron shuttle for autotrophic

期刊论文

Enhancement of extracellular Cr(VI) reduction for anammox recovery using hydrazine: performance, pathways

期刊论文

Integrated energy view of wastewater treatment: A potential of electrochemical biodegradation

期刊论文

Electroactivity of the magnetotactic bacteria AMB-1 and MSR-1

期刊论文

Insights into the electron transfer mechanisms of permanganate activation by carbon nanotube membrane

期刊论文

precise-acting” strategies for improving anaerobic methanogenesis of organic waste: Insights from the electrontransfer system of syntrophic partners

期刊论文

Potential of electron transfer and its application in dictating routes of biochemical processes associated

期刊论文

Algal biomass derived biochar anode for efficient extracellular electron uptake from

Yan-Shan Wang, Dao-Bo Li, Feng Zhang, Zhong-Hua Tong, Han-Qing Yu

期刊论文

4-Amino-1,8-naphthalimide based fluorescent photoinduced electron transfer (PET) pH sensors as liposomal

Miguel Martínez-Calvo, Sandra A. Bright, Emma B. Veale, Adam F. Henwood, D. Clive Williams, Thorfinnur Gunnlaugsson

期刊论文

Sulfur cycle as an electron mediator between carbon and nitrate in a constructed wetland microcosm

Wenrui Guo, Yue Wen, Yi Chen, Qi Zhou

期刊论文

Synthesis, spectroscopic, and electrochemical properties of two dyads consisted of tetrathiafulvalene and carbazole

Guoqiao LAI, Yibo LIU, Meijiang LI, Yongjia SHEN

期刊论文

Decellularized extracellular matrix mediates tissue construction and regeneration

期刊论文

Biosorption of Cu(II) to extracellular polymeric substances (EPS) from

Xiangliang PAN, Jing LIU, Wenjuan SONG, Daoyong ZHANG

期刊论文

流动电极微生物电合成提高产物生成速率及降低能量消耗

褚娜, 王东麟, 王厚锋, 梁勤军, 常佳丽, 高瑜, 蒋永, 曾建雄

期刊论文